DEFINE - Declare a variable (short: DEF)
DESCRIBE - Lists the attributes of tables and other objects (short: DESC)
EDIT - Places you in an editor so you can edit a SQL command (short: ED)
EXIT or QUIT - Disconnect from the database and terminate SQL*Plus
GET - Retrieves a SQL file and places it into the SQL buffer
HOST - Issue an operating system command (short: !)
LIST - Displays the last command executed/ command in the SQL buffer (short: L)
PROMPT - Display a text string on the screen. Eg prompt Hello World!!!
RUN - List and Run the command stored in the SQL buffer (short: /)
SAVE - Saves command in the SQL buffer to a file. Eg "save x" will create a script file called x.sql
SET - Modify the SQL*Plus environment eg. SET PAGESIZE 23
SHOW - Show environment settings (short: SHO). Eg SHOW ALL, SHO PAGESIZE etc.
SPOOL - Send output to a file. Eg "spool x" will save STDOUT to a file called x.lst
START - Run a SQL script file (short: @)
source :
http://www.orafaq.com/wiki/SQL*Plus_FAQ